A Mechanistically Deceiving Formation of Aryl(1-indanyl)ketones via Acid-Catalyzed Cyclization of ortho-Alkynylarylmethanols

20 Sep 2023
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A Mechanistically Deceiving Formation of Aryl(1-indanyl)ketones via Acid-Catalyzed Cyclization of ortho-Alkynylarylmethanols

Rodphon W, Linkhum S, Thongsornkleeb C, Tummatorn J, Ruchirawat S

J Org Chem. 2023;88(7):4172-4186.

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Nimnual, P.; Norseeda, K.; Akkachairin, B.; Tummatorn, J.; Laohapaisan, P.; Supantanapong, N.; Chuangsoongnern, P.; Thongsornkleeb, C.; Sittihan, S.; Ruchirawat, S.; Rodphon, W., Synthesis of β-Naphthols and Naphthofuranones from o-Alkynylarylketones via Sequential AgTFA-Catalyzed Ketonization-Intramolecular Aldol Condensation: Total Synthesis of Negundin A. Asian J. Org. Chem. 2018, 7, 932-945.
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Nimnual, P.; Norseeda, K.; Akkachairin, B.; Tummatorn, J.; Laohapaisan, P.; Supantanapong, N.; Chuangsoongnern, P.; Thongsornkleeb, C.; Sittihan, S.; Ruchirawat, S.; Rodphon, W., Synthesis of β-Naphthols and Naphthofuranones from o-Alkynylarylketones via Sequential AgTFA-Catalyzed Ketonization-Intramolecular Aldol Condensation: Total Synthesis of Negundin A. Asian J. Org. Chem. 2018, 7, 932-945.

Nimnual, P.; Norseeda, K.; Akkachairin, B.; Tummatorn, J.; Laohapaisan, P.; Supantanapong, N.; Chuangsoongnern, P.; Thongsornkleeb, C.; Sittihan, S.; Ruchirawat, S.; Rodphon, W., Synthesis of β-Naphthols and Naphthofuranones from o-Alkynylarylketones via Sequential AgTFA-Catalyzed Ketonization-Intramolecular Aldol Condensation: Total Synthesis of Negundin A. Asian J. Org. Chem. 2018, 7, 932-945.
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